| 1 | October 01, 2020 CET: 21:00 | Valencia Basket VAL | 65-63 | LDLC ASVEL Villeurbanne ASV |
| 2 | October 08, 2020 CET: 21:00 | Real Madrid RMB | 77-93 | Valencia Basket VAL |
| 3 | October 13, 2020 CET: 21:00 | Valencia Basket VAL | 66-71 | FC Barcelona BAR |
| 4 | December 08, 2020 CET: 21:00 | Valencia Basket VAL | 72-85 | Zenit St Petersburg ZEN |
| 5 | October 22, 2020 CET: 19:00 | Zalgiris Kaunas ZAL | 82-94 | Valencia Basket VAL |
| 6 | October 29, 2020 CET: 18:00 | CSKA Moscow CSK | 84-75 | Valencia Basket VAL |
| 7 | November 06, 2020 CET: 21:00 | Valencia Basket VAL | 86-81 | AX Armani Exchange Milan AXM |
| 8 | November 13, 2020 CET: 20:30 | FC Bayern Munich BAY | 90-79 | Valencia Basket VAL |
| 9 | November 17, 2020 CET: 21:00 | Valencia Basket VAL | 95-83 | Panathinaikos OPAP Athens PAO |
| 10 | November 20, 2020 CET: 21:00 | Valencia Basket VAL | 82-80 | Maccabi Playtika Tel Aviv MTA |
| 11 | November 27, 2020 CET: 18:45 | Fenerbahce Beko Istanbul FBI | 86-90 | Valencia Basket VAL |
| 12 | December 03, 2020 CET: 21:00 | Valencia Basket VAL | 92-100 | ALBA Berlin ALB |
| 13 | December 10, 2020 CET: 21:00 | Valencia Basket VAL | 76-74 | Anadolu Efes Istanbul EFE |
| 14 | December 16, 2020 CET: 20:30 | Olympiacos Piraeus OLY | 85-96 | Valencia Basket VAL |
| 15 | December 18, 2020 CET: 19:00 | Crvena Zvezda mts Belgrade CZV | 76-73 | Valencia Basket VAL |
| 16 | December 23, 2020 CET: 21:00 | Valencia Basket VAL | 88-82 | Khimki Moscow Region KHI |
| 17 | December 29, 2020 CET: 21:00 | TD Systems Baskonia Vitoria-Gasteiz TDB | 71-70 | Valencia Basket VAL |
| 18 | January 07, 2021 CET: 21:00 | FC Barcelona BAR | 89-72 | Valencia Basket VAL |
| 19 | January 12, 2021 CET: 20:45 | AX Armani Exchange Milan AXM | 95-80 | Valencia Basket VAL |
| 20 | January 15, 2021 CET: 21:00 | Valencia Basket VAL | 91-71 | Crvena Zvezda mts Belgrade CZV |
| 21 | January 21, 2021 CET: 20:45 | LDLC ASVEL Villeurbanne ASV | 90-77 | Valencia Basket VAL |
| 22 | January 27, 2021 CET: 21:00 | Valencia Basket VAL | 78-79 | Zalgiris Kaunas ZAL |
| 23 | January 29, 2021 CET: 20:00 | Panathinaikos OPAP Athens PAO | 91-72 | Valencia Basket VAL |
| 24 | February 04, 2021 CET: 21:00 | Valencia Basket VAL | 105-103 | CSKA Moscow CSK |
| 25 | February 19, 2021 CET: 21:00 | Valencia Basket VAL | 89-78 | Real Madrid RMB |
| 26 | February 25, 2021 CET: 18:00 | Zenit St Petersburg ZEN | 62-91 | Valencia Basket VAL |
| 27 | March 02, 2021 CET: 18:30 | Anadolu Efes Istanbul EFE | 99-83 | Valencia Basket VAL |
| 28 | March 04, 2021 CET: 20:05 | Maccabi Playtika Tel Aviv MTA | 84-72 | Valencia Basket VAL |
| 29 | March 12, 2021 CET: 21:00 | Valencia Basket VAL | 0-0 | Fenerbahce Beko Istanbul FBI |
| 30 | March 19, 2021 CET: 18:00 | Khimki Moscow Region KHI | 0-0 | Valencia Basket VAL |
| 31 | March 25, 2021 CET: 21:00 | Valencia Basket VAL | 0-0 | FC Bayern Munich BAY |
| 32 | March 31, 2021 CET: 21:00 | Valencia Basket VAL | 0-0 | Olympiacos Piraeus OLY |
| 33 | April 02, 2021 CET: 20:00 | ALBA Berlin ALB | 0-0 | Valencia Basket VAL |
| 34 | April 08, 2021 CET: 21:00 | Valencia Basket VAL | 0-0 | TD Systems Baskonia Vitoria-Gasteiz TDB |
